Preheat to 350°F. then line an 8x8-inch metal pan with parchment and set aside.
In a heatproof bowl, combine butter, chopped chocolate, and oil. Melt gently (microwave in 30 sec bursts or over a double boiler), then stir in cocoa powder and the espresso powder until smooth. Let it cool slightly.
½ cup butter, 3 tbsp neutral oil, 4 oz 70% dark chocolate, chopped, 2/3 cup Dutch process cocoa powder, 1 tsp instant espresso powder
In a large bowl, beat eggs, yolk, granulated sugar, powdered sugar, and vanilla on high speed for 3-6 minutes until thick, pale, and ribbon-y. This is where that shiny crackle top is born!
2 large eggs , 1 egg yolk, 1 cup granulated sugar, ½ cup powdered sugar, 1½ tsp vanilla extract
With the mixer on low, slowly pour in the slightly cooled chocolate-butter mixture.
Sift the dry ingredients into the brownie batter mixture. Gently fold into the batter with a spatula.
½ cup all-purpose flour, 1 tbsp cornstarch, ½ tsp kosher salt
Pour the batter into the prepared pan, smooth the top, and tap the pan once on the counter. Bake 23-25 minutes, or until a toothpick comes out with moist crumbs
Let the brownies cool completely in the pan before adding any toppings. Adding the peanut butter layer to warm brownies will cause it to soften and lose structure.